1.

In case of octahedral compex, if the e_(g) orbitals (d_(x^(2) - y^(2)) " and " d_(z^(2))) are asymmetricaaly filled, their degeneracy is destroyed and the ligands approaching along +Z and -Z directions experiences different amount of repulsions than the ligands approaching along the +X, -X, +Y " and " -Y directions. As a result, the symmetrical nature of such complexes is lost and either elongation or compression along Z-axis taken place. Answer the following three questions based on the above situation. Which of the following is incorrect regarding K_(4) [Cr F_(6)] ?

Answer»

It has two long and FOUR short `CR-F` bonds
It has four long and two short `Cr-F` bonds
SPIN only magnetic moment of the COMPLEX is approximately `4.9 Bm`
If `Cr` is replaced by `Cu`, similar types of deformation in the regular octahedral geometry are observed

Answer :B


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