1.

In case of octahedral compex, if the e_(g) orbitals (d_(x^(2) - y^(2)) " and " d_(z^(2))) are asymmetricaaly filled, their degeneracy is destroyed and the ligands approaching along +Z and -Z directions experiences different amount of repulsions than the ligands approaching along the +X, -X, +Y " and " -Y directions. As a result, the symmetrical nature of such complexes is lost and either elongation or compression along Z-axis taken place. Answer the following three questions based on the above situation. In which of the following case, no such elongation or compressions are expected ?

Answer»

`d^(4)` - weak LIGANDS
`d^(5)`- weak ligands
`d^(7)`- STRONG ligands
`d^(9)`- strong or weak ligands

Answer :B


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