1.

In the following pairs of halogen compounds, which compound undergoes faster S_(N)1 reaction?

Answer»

Solution :The `S_(N)1` reaction procceeds through Stable Carbocation intermediate. GREATER is the Stability of Carbocation, greater is the reactivity. Thus order of reactivity of alkyl HALIDE is :
`3^(@)R-X gt 2^(@)R-X gt 1^(@)R-X`
(i) will REACT faster because is more stable.
(ii) REACTS faster due to the greater stability of `2^(@)` - carbocation as compared to `1^(@)` - carbocation.


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