1.

In the series of reaction C_(6)H_(5)NH_(2)underset(0-5^(@)C)overset(NaNO_(2)//HCl)rarrXunderset(CH_(2)O)overset(HNO_(2))rarrY+N_(2)+HClX and Y are respectively.

Answer»

`C_(6)H_(5)-N=N-C_(6)H_(5),C_(6)H_(5)N_(2)^(o+)CL^(o+)`
`C_(6)H_(5)N_(2)^(o+)Cl^(o+),C_(6)H_(5)-N=N-C_(6)H_(5)`
`C_(6)H_(5)N_(2)^(o+)Cl^(o+),C_(6)H_(5)NO_(2)`
`C_(6)H_(5)NO_(2),C_(6)H_(6)`

SOLUTION :`C_(6)H_(5)NH_(2)UNDERSET(0^(@)C-5^(@)C)overset(NaNO_(2)//HCl)rarrH_(5)N_(2)^(+)Cl^(-)underset(H_(2)O)overset(HNO_(2))rarr`
`C_(6)H_(5)NO_(2)+N_(2)+HCl`


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