1.

In the valence bond theory, hybridisation of orbitals is an integral part of bond formation.Hybridisation consists of mixing or linear combination of the "pure" atomic orbitals in such a way as to form new hybrid orbitals such as sp, sp^2, sp^3, sp^3d , sp^3d^2 etc. Now answer the following questions : Which of the following atomic orbitals does not participitate in trigonal bipyramidal hybridisation i.e. sp^3d hybridisation ?

Answer»

s
`d_(x^2-y^2)`
`p_x`
`p_y`

Solution :`{:("HYBRIDISATION","Atomic orbitals","Bond angles","Geometry"),(SP,s+"arbitarary"p^n,180^@,"LINEAR"),(sp^2,s+"arbitarary"p^n,120^@,"Trigonal"),(sp^3,s+"arbitarary"p^n,109.5^@,"Tetrahedral"),(sp^3d,d_((z)^2)+s+p_x+p_y+p_z,90^@","120^@,"Trigonal bipyramidal"),(sp^3d^2,d_((z)^2)+d_(x^2-y^2)+s+p_x+p_y+p_z,90^@,"Octahedral") :}`


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