1.

In thesyudy of cholrinatio of propane, fourproducts (A,B Cand D of the formula C_(3)H_(6)Cl_(2) were isolated Each was Futherchorinated toprovetrichloro products (C_(3)H_(5)Cl_(3)) it wasfoundthat A provided one trichoro Product ,B gave two and C and D each gave three whatt are the structural formula of A, B ,C and D?

Answer»

SOLUTION :Dichoro isomers,
`(A) {:(""Cl),(""|),(" "CH_(3)-C-CH_(3)),(""|) ,(""Cl),(""darrCl_(2)),(""Cl),(""|),(CH_(2)Cl-C-CH_(3)),(""|),(""Cl),("(one)"):} (B) {:(""ClCH_(2)CH_(2)CH_(2)Cl),(""darrCl_(2)),(1.Cl_(2)CHCH_(2)CH_(2)Cl_(2)),(2.ClCH_(2)ClCHCH_(2)Cl):}`
`( C) {:(CH_(3)CHClCH_(2)Cl),(""darrCl_(2)),(1.CH_(2)ClCHClCH_(2)Cl),(2.CH_(3)CHClCHCl_(2)),(3. CH_(3)C Cl_(2)CH_(2)Cl):} (D) {:(CH_(3)CH_(2)XHXl_(2)),(""darr Cl_(2)),(1. CH_(3)CHClCHCl_(2)),(2.CH_(3)CH_(2)CCl_(3)):}`


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