1.

In which of the following cases will a violet colouration be observed?

Answer»

An alkaline solution of sodiumnitroprusside is treated with a solution of `Na_(2)S`
a solution of sodiumnitroprusside in aq.NaOH is treated with `Na_(2)SO_(3)`
a solution of cobalt NITRITE treated with KCI.
a solution of `Mn(NO_(3))_(2)` is treated with sodium bismuthate (or) red LEAD in presence of conc. `HNO_(3)`

Solution :`Mn(HO_(3))_(2)+6HNO_(3)+5NaBiO_(3) to Na_(4)[FE(CN)_(5)NOS]` (violet colour)


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