1.

In which of the following complexes more than one type of structural isomers is possible :

Answer»

`[Co(NH_3)_5(NO_2)]Cl`
`[Co(NH_3)_5(H_2O)](NO_2)_3`
`[Pt(NH_3)_4 ] Pt (SCN)_4`
`[Cr(dmg)_3]`

Solution :A`to`lingage , ionisation isomerism
B`to`hydrate, LINKAGE isomerism
C`to` linkage , COORDINATION isomerism
(B)STP REFERS to a TEMPERATURE of 273 K & Nermst EQN. mentioned is at 298 K
(D)`lambda_(mBa(OH_2))^(oo)=lambda_(mBa^(2+))^(oo)+2lambda_(mOH^(-))^(oo)`


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