1.

In which of the following method of purification, metal is converted to its volatile compound which is decomposed to give pure metal ?

Answer»

Heating with stream of carbon monoxide. 
Heating with iodine. 
Liquation. 
DISTILLATION

Solution :Mond.s carbonyl process :
`underset("(impure)")(N i) +4CO overset(330 - 350 K)(RARR) N i(CO)_(3)`
`N i + (CO) overset(450 - 470 K)(rarr) underset("(pure)")(N i) + 4CO`.
Van-Arkel method :
`underset("(impure)")(Zr) + 2I_2 to ZrI_4`
`ZrI_4 overset(1800K)(rarr) underset("(pure)") (Zr )+ 2I_2`.


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