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Indentify the following ions by a simple test forming complex compound : (i)Cu^(2+)(ii)Ni^(2+)(iii)Fe^(3+)(iv)Co^(2+) |
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Answer» Solution :(i) ` Cu^(2+) ` solution with excesses of AMMONIA solution, `NH_(4)OH` FROMS a deep BLUE coloured complex. ` underset(ap)(Cu^(2+)) + 4NH_(4)OH_(aq) to [Cu(NH_(3))_(4)]^(2+) + 4H_(2)O` (b) ` Cu^(2+)` with potassium hexacyanoferrate (II) forms red - brown PRECIPITATE which is a complex, ` Cu_(2) [Fe(CN)_(6)]` ` 2Cu^(2+) + K_(4)[Fe(CN)_(6)] to Cu_(2)[Fe(CN)_(6)]` red brown (ii) `Ni^(2+)`with dimethylgloxine (DMG) in ammonical alcoholic solution forms rosy-red precipitate of a complex. ` (##NVT_21_CHE_XII_C18_E01_001_S01.png" width="80%"> (iii) (a) ` Fe^(3+) ` with `K_(4)[Fe (CN)_(6)]`forms prussian blue compound of deep blue colour . ` Fe^(3+) + K_(4)[Fe(CN)_(6)] to overset(III""II )(K[Fe(CN)_(6))] + 3K^(+)` prussian blue (b) ` Fe^(3+) ` with ammonium thiocyanate `NH_(4)SCN` forms deep red compound . ` Fe^(3+) + 3NH_(4)SCN to underset("deep red")(Fe(SCN)_(3)) + 3NH_(4)^(+)` |
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