1.

Indicate the types of isomerism exhibited by the following complexes and draw the structures for these isomers : [Co(NH_(3))_(5)(NO_(2))](NO_(3))_(2)

Answer»

Solution :Ionisation isomers of the COMPOUND are given below :
`[Co(NH_(3))_(5)(NO_(2))](NO_(3))_(2),[Co(NH_(3))_(5)(NO_(3))](NO_(2))(NO_(3))`
Linkage isomers of the compound are SHOWN below :
`(Co(NH_(3))_(5)(NO_(2))](NO_(3))_(2), [Co(NH_(3))_(5)(ONO)](NO_(3))_(2)`
OCTAHEDRAL complexes of the TYPE `[MA_(5)B]` do not show geometrical and optical ISOMERISM.


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