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Justify that peroxymono and peroxydisulphuric acids have a peroxy linkage. How are they structurally diffferent? |
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Answer» Solution :The peroxymono and peroxydisulphuric acid may be considered to have been DERIVED from `H_(2)O_(2)` by REPLACING one H and both H by `HSO_(3)` groups respectively. `H_(2)SO_(5)` the monoacid and`H_(2)S_(2)O_(8)` the peroxydisulphuric acid, both on hydrolysis YIELD `H_(2)O_(2)`. Both permono and perdi sulphuric acids contain `-O-O-` linkage in their molecular structure. |
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