1.

K_(f) for water is 1.86^(@)C*m^(-1). What is the molality of a solutionn which freezes at -0.192^(@)C? Assuming no change in the solute by raising the temperature, at what temperature will the solution boil ? (K_(b) for H_(2)O=0.515^(@)C*m^(-1))

Answer»

SOLUTION :MOLALITY `=(DeltaT_(f))/(K_(f))`
`=(0.192)/(1.86)=0.103m`
Again `DeltaT_(B)=K_(b).m` …………(Eqn. 8)
`=0.515xx0.103=0.0532^(@)C`
Assuming the b.p. of pure water to be `100^(@)C` the b.p. of the solution will be `100.0532^(@)C`


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