1.

Ligands are broadly classified into two classes classical and non-classical ligands, depending on their donor annd acceptor ability. Classical ligands form classical complexes while non-classical ligands form non-classical complex. Bonding mechanism in non-classical is called synergic bonding. Q. Synergic bonding is absent in:

Answer»

`[Mo(CO)_(6)]`
`[CR(CO)_(3)(B_(3)N_(3)H_(6)]`
`[Sc(CO)_(6)]^(3+)`
`[NI(CN)_(4)]^(4-)`

Solution :`overset(+III)(Sc):3d^(@)4S^(@)`, as d-orbitals at `overset(+III)(Sc)` are empty, hence, there is no synergic bonding in `[Sc(CO)_(6)]^(3+)`.


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