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Lithium metal has a body centred cubic structure. Its density is 0.53g cm^(-3) and its molar mass is 6.94g mol^(-1). Calculate the volume of a unit cell of lithium metal. |
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Answer» SOLUTION :For bcc unit CELL, Z=2 DENSITY (d)=0.53 G `cm^(-3)` Molar mass, M=6.94 g `mol^(-1)` Mass of an atom = `(6.94)/(6.023 xx 10^(23)) = 1.152 xx 10^(-23)g` Mass of unit cell = `2 xx 1.152 xx 10^(-23) = 2.304 xx 10^(-23) g` Volume of unit cell = `("Mass")/("Density")=(2.304 xx 10^(-23))/(0.53) cm^3` `= 4.35 xx 10^(-23) cm^3` |
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