1.

Match each set of hybrid orbitals from List-I with complex given in list II

Answer»

P-5, Q-4,6, R--2,3, S--1
P--5,6, Q--4, R--3, S--1,2,
P--6, Q--4,5, R--1, S--2,3,
P--4,6, Q--5,6, R--1,2, S--3

Solution :1) `[FeF_(6)]^(4-) 3d^(6)` & WEAK field ligand `therefore` HYBRIDISATION: `sp^(3)d^(2)` ,
2) `[ti(H_(2)O)_(3)Cl_(3)]` & weak field ligand `therefore` Hybridisation: `d^(2)sp^(3)`.
3) `[Cr(NH_(3))_(6)]^(3+)`, `3d^(3)` & strong field ligand `therefore` Hybridisation: `d^(2)sp^(3)`
4) `[FeCl_(4)]^(2-) 3d^(6)` & weak field ligand `therefore` Hybridisation: `sp^(3)`
5) `Ni(CO)_(4)`, `3d^(10)` `therefore` Hybridisation: `sp^(3)`
6) `[Ni(CN)_(4)]^(2-)`, `3d^(8)` `therefore` Hybridisation, `dsp^(2)`


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