1.

Match List I (Equations) with List-II (Type of process) and select the correct option{:(,"List I",,"List II"),(,"Equations",,"Type of processes"),(1.,K_(p)gtQ,(i),"Non-spontaneous"),(2.,DeltaG^(@)ltRTlnQ,(ii),"Equilibrium"),(3.,K_(P)=Q,(iii),"Spontaneous and endothermic"),(4.,Tgt(DeltaH)/(DeltaS),(iv),"Spontaneous"):}

Answer»

1(i), 2(ii), 3(iii), 4(iv)
1(iii), 2(iv), 3(ii), 4(i)
1(iv), 2(i), 3(ii), 4(iii)
1(ii), 2(i), 3(iv), 4(iii)

Solution :`K_(p) gt Q rarr` Reaction moves in forward direction
`DELTAG^(@) lt RT ln Q, DeltaG=+ve=` reaction non-SPONTANEOUS
`K_(P)=Q=` Reaction is equilibrium
`Tgt(DeltaH)/(DeltaS)=DeltaH=+ve`,endothermic
THUS, `DeltaHltTDeltaS` spontaneous.


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