1.

Match the transformation in colums I with appropriate options in column II. `{:("Column I" ,"Column II"),((A)CO_(2)(s) rarr CO_(2)(g),(p)"phase transition"),((B)CaCO_(3)(s)rarr CaO(s) + CO_(2)(g) ,(q)"allotropic change"),((C)2H.rarrH_(2)(g),(r)DeltaH "is positive"),((D)P_(("white, solid"))rarr P_(("red,solid")),(s)DeltaS "is positive"),(,(t) DeltaS "is negative"):}`

Answer» Correct Answer - A::B::C::D
`(A) CO_(2)(s) rarr CO_(2)(g)`
It is phase transition . The process is endothermic (sublimation).
Gas is produced , so entropy increases.
(B) On heating `CaCO_(2)` decomposes. So process is endothermic . The enthropy increases as gaseous product is formed.
(C) `2H.rarr H_(2)(g)`
Entropy decreases as number of gaseous particles decreases.
(D) It is phase transition.
Red P is more stable than while. So `DeltaH "is" -ve`.


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