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Mixture 'X' containing 0.02 mole of [Co(NH_(3))_(5)SO_(4)]Br and 0.02 mole of [Co(NH_(3))_(5)Br]SO_(4) was dissolved in water to get 2 lit of solution. If 1 lit of X+ execss AgNO_(3)toY mole of ppt. and 1 lit of X+ excess BaCl_(2)toZ mole of ppt. Number of mole of Y and Z are

Answer»

0.01, 0.01
0.02, 0.01
0.01, 0.02
0.02, 0.02

Solution :1 lit. of solution CONTAINS 0.01 mole of each
`[Co(NH_(3))_(5)SO_(4)]Br and [Co(NH_(3))_(5)Br]SO_(4)`
`[Co(NH_(3))_(5)UNDERSET(0.01)(SO_(4))]Br+HgNO_(3)tounderset(0.01)(AgBr)darr+[Co(NH_(3))_(5)SO_(4)]NO_(3)`
`[Co(NH_(3))_(5)underset(0.01)Br]SO_(4)+BaCl_(2)tounderset(0.01)(BaSO_(4))darr+[Co(NH_(3))_(5)Br]Cl_(2)`


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