Saved Bookmarks
| 1. |
Molar conductivity of an electrolyte is the conductance of all the ions produced by one gram mole of the electrolyte in solution and is denoted as Lambda_(m). Lambda_(m)=(kxx1000)/(c ) Here k is the specific conductance while c is the molar concentration of the electrolyte. The molar conductance of the strong electrolytes at infinite dilution (Lambda_(m)^(oo)) can be obtained graphically by extrapolation while the same for weak electrolytes cannot be obtained graphically. It can be calculated theoretically with the help of Kohrausch's. Law. Lambda_(m(AxBy))^(oo)=xlambda_(m (A^(y+)))^(oo)+ylambda_(m(B^(x)))^(oo) 48250 C of electricity was required to deposit all the copper present in 0.5 L of CuSO_(4) solution using inert electrodes. The molarity of solution was (Assume volume constant). |
|
Answer» 0.50 M `2xx96500" C"` of charge deposit Cu=63 g 48250 C of charge deposit Cu `=((63 g)xx(48250" C"))/((2xx96500" C"))=15.75" g"`b Molarity (M)`=(((15.75 g))/((63.0 g" MOL"^(-1))))/((0.5 L))` =0.5 mol `L^(-1)`=0.5 M |
|