1.

Molar conductivity of an electrolyte is the conductance of all the ions produced by one gram mole of the electrolyte in solution and is denoted as Lambda_(m). Lambda_(m)=(kxx1000)/(c ) Here k is the specific conductance while c is the molar concentration of the electrolyte. The molar conductance of the strong electrolytes at infinite dilution (Lambda_(m)^(oo)) can be obtained graphically by extrapolation while the same for weak electrolytes cannot be obtained graphically. It can be calculated theoretically with the help of Kohrausch's. Law. Lambda_(m(AxBy))^(oo)=xlambda_(m (A^(y+)))^(oo)+ylambda_(m(B^(x)))^(oo) 48250 C of electricity was required to deposit all the copper present in 0.5 L of CuSO_(4) solution using inert electrodes. The molarity of solution was (Assume volume constant).

Answer»

0.50 M
2.50 M
0.25 M
1.0 M

Solution :(a) `Cu^(2+)(aq)+UNDERSET(2F)2e^(-) to underset(63 g)(Cu(s))`
`2xx96500" C"` of charge deposit Cu=63 g
48250 C of charge deposit Cu
`=((63 g)xx(48250" C"))/((2xx96500" C"))=15.75" g"`b
Molarity (M)`=(((15.75 g))/((63.0 g" MOL"^(-1))))/((0.5 L))`
=0.5 mol `L^(-1)`=0.5 M


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