1.

Molar conductivity of an electrolyte is the conductance of all the ions produced by one gram mole of the electrolyte in solution and is denoted as Lambda_(m). Lambda_(m)=(kxx1000)/(c ) Here k is the specific conductance while c is the molar concentration of the electrolyte. The molar conductance of the strong electrolytes at infinite dilution (Lambda_(m)^(oo)) can be obtained graphically by extrapolation while the same for weak electrolytes cannot be obtained graphically. It can be calculated theoretically with the help of Kohrausch's. Law. Lambda_(m(AxBy))^(oo)=xlambda_(m (A^(y+)))^(oo)+ylambda_(m(B^(x)))^(oo) Which of the following solution of KCl will have the maximum value of specific conductance ?

Answer»

1.0 N
0.1 N
`1.0xx10^(-2)" N"`
0.5 N.

Solution :(a) SPECIFIC CONDUCTANCE (k) is directly proportional to the number of ions per unit volume. 1.0 NKCl will GIVE maximum number of ions in solution.


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