1.

NCl_(3) gets readily hydrolysed while NF_(3) does not. Why?

Answer»

SOLUTION :In `NCl_(3), CL` has vacant d - orbitals to accpet the lone pair of electrons DONATED by O - atom of `H_(2)O` MOLECULES but in `NF_(3)F` does not have d - orbitals.
`NCl_(3)+3H_(2)Orarr NH_(3)+3HOCl`,
`NF_(3)+H_(2)Orarr"No reaction."`


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