1.

Nitration of aniline in strongly acidic medium, results in the formation of m-nitroaniline also. This is because

Answer»

amino GROUP is meta orienting during electrophilic substitution reaction
nitro group goes always to the meta position IRRESPECTIVE of the substituents.
nitration of aniline is a NUCLEOPHILIC substitution reaction in strongly acidic medium.
in strongly acidic conditions aniline is PRESENT as anilinium ion

Solution :See reduction of nitrobenzene.


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