1.

Nitric acid acts only as an oxidising agent while nitrous acid acts both as an oxidising as well as a reducing agent. Why?

Answer»

(i) Nitric Acid HNO3

Here Oxidation number of N is HNO3 = +5; But Maximum oxidation number of N = +5; Minimum oxidation number of N = -3 Since the oxidation number of N in HNO3 is maximum (+5), 

therefore it can only decrease by accepting electrons. Hence HNO3 acts only as an oxidizing agent. 

(ii) Nitrous Acid HNO2

Here Oxidation number of N in HNO2 = +3 Maximum oxidation number of N = +5; Minimum oxidation number of N = -3 Thus, the oxidation number of N can either increase by losing electrons or can decrease by accepting electrons. 

Therefore, HNO2 acts both as an oxidizing as well as a reducing agent.



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