1.

Observe the esterfication mechanisms for primary and tertiary alcohols. CH_3-COOH+C_2H_6overset(18)OHoverset(Conc.H_2SO_4)to(P) CH_3-COOH+(CH_3)_3C-overset(18)OHoverset(Conc.H_2SO_4)(Q) In the above reaction (P) and (Q) are respectively :

Answer»

<P>`CH_3-oversetoverset(O)(||)C-O-C_2H_6,CH_3-oversetoverset(O)(||)C-overset(18)(O)-undersetunderset(CH_3)(|)oversetoverset(CH_3)(|)C-CH_3`
`CH_3-oversetoverset(O)(||)C-overset(18)(O)-C_2H_5,CH_3-oversetoverset(O)(||)C-O-undersetunderset(CH_3)(|)oversetoverset(CH_3)(|)C-CH_3`
`C_2H_5-oversetoverset(O)(||)C-overset(18)(O)-CH_3, CH_3-oversetoverset(O)(||)C-O-undersetunderset(CH_3)(|)oversetoverset(CH_3)(|)C-CH_3`
`CH_3-oversetoverset(O)(||)overset(18)(O)-C_2H_6,CH_3-oversetoverset(O)(||)C-overset(18)(O)-undersetunderset(CH_3)(|)oversetoverset(CH_3)(|)C-CH_3`

Solution :P is formed by type-1 MECHANISM and Q is formed by type-2 mechanism.


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