1.

Out of chlorobenzene and chloromethane which is more reactive towards nucleophilic substitution reactions.

Answer»

Solution :CHLOROBENZENE can be regarded as a RESONANCE hybrid of five structure. As a result, C-Cl bond in chlorobenzene has some DOUBLE bond CHARACTER and hence more difficult to break than C-Cl bond in chloromethane `(CH_(3)-Cl)` which has pure SINGLE bond character.


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