1.

Out of o-nitrophenol and o-cresol which is more acidic?

Answer»

SOLUTION :Due to -I and -R-effect of the `NO_(2)` GROUP, electron density in the O-H bond decreases while due to +I or hyperconjugation effect, of the `CH_(3)` group, the electron density in the O-H bond increases.

As a RESULT, O-H bond is o-nitrophenol is much weaker than the O-H bond is o-cresol and HENCE o-nitrophenol is much more acidic than o-cresol.


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