1.

p-methoxylbenzyl bromide reacts faster than p-nitrobenzyl bromide with ethanol to form an ether product. Explain, why ?

Answer»

Solution :
METHOXY GROUP is ELECTRON releasing, therefore, it stabilises carbocation formed by p-methoxybenzyl BROMIDE whereas nitro group being electron withdrawing destabilises carbocation formed by p-nitro BENZYL bromide. That is why p-methoxybenzyl bromide is more reactive than p-nitrobenzyl bromide.


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