1.

PCl_(5) is ionic in nature in the solid state. Give reasons.

Answer»

Solution :`PCl_(5)` conducts electricity in the molten state. This MEANS that in the solid state it CONSISTS of ions.
`2PCl_(5)rarr [PCl_(4)]^(+)[PCl_(6)]^(-)`.
On melting, these ions BECOMES free to move and hence `PCl_(3)` conducts electricity in the molten state.


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