1.

pH calculation upon dilute of strong acid solution is generally done by equating n_(H) in original solution & diluted solution.However . If strong acid solution is very dilute then H^(+) from water are also to be considered take log3.7=0.568 and answer the following questions. A 1 litres solution of pH=4(solution ofa strong acid ) is added to the 7//3 litres of water.What is the pH of resulting solution?

Answer»

`4.52`
`4.365`
`4.4`
`4.432`

Solution :INITIAL `pH=4`
`[H^(+)]=10^(-4)`
`N_(1)V_(1)=N_(2)V_(2)rArr 10^(-4)=N_(2)xx[1+(7)/(3)]`
`10^(-4)=N_(2)xx(10)/(3)rArr N_(2)=3xx10^(-5)"" gt10^(-6)`
so `[H^(+)]` of WATER is not consider
`[H^(+)]=3xx10^(-5)`"" so""`pH=5-log(3)`""`=5-0.48=4.52`


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