1.

Ph-CH_2-oversetoverset(CH_3)(|)CH-CH_3underset(("monochlorination"))overset(Cl//hv)to Which statements is/are correct about photochemical chlorination of the above compound ?

Answer»

The major product will be chiral carbon atom having OPTICALLY inactive compound
The intermediate free radical of the major product is resonance STABILISED
The intermediate free radical is tertiary
The intermediate free radical is planar , and stabilised by only hyperconjugation

Solution :Free radical MECHANISM `Ph-CH_2-undersetunderset(CH_3)(|)CH-CH_3` give THREE type of alkyl radicals


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