1.

Phenols are more acidic than alcohols and CH_(3)NO_(2) because

Answer»


which is the conjugate base of phenol is more stable than `Coverset(Ө)H_(2)-NO_(2)`

In the phenoxide , the negative charge is on OXYGEN atom having greater UNOCCUPIED surface volume than in `Coverset(Ө)H_(2)-NO_(2)` where the -ve charge is on a LESSER unoccupied surface volume of carbon thereby making

Solution :
isresonance stabilized , while in `R-O^(Ө)` DUE to +I effect the `R-O^(Ө)` is destabilized . The conjugate base of `CH_(3)NO_(2)` is
`overset(Ө)CH_(2)-NO_(2)` which is RESONANCE sbabilized

out of `-underset(..)overset(..)O-H` group whose conjugate base is `-O^(Ө)` and `-underset(|)overset(|)C^(Ө)` because the charge density is less in `-O^(Ө)` than in`-underset(|)overset(|)C^(Ө)` due to greater surface volume available on `-O^(Ө)` than in `-underset(|)overset(|)C^(Ө)`
is more acidic than ROH and `CH_(3)NO_(2)` . Hence choices (a),(b) and (d) are correct while (c) is incorrect.


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