1.

Prove that cp is greater than cv.

Answer»

Out of the two specific heats of a gas, 

Cp > Cv

This can be understood as follows:

In case Cv volume of the gas is kept constant and heat is required only for raising the temperature of gas through 1°C or 1K. No heat whatsoever is spent in expansion of the gas.

In case of CP as pressure of the gas is kept constant and the gas could expand on heating. 

∴ Some heat is spent in expansion of the gas against external pressure.

Hence, more heat is required to raise the temperature of 1 gm mole of the gas through 1°C or 1K when heated at constant pressure. Hence, Cp > Cv .



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