1.

Prove that the time required for the completion (3^(th))/(4) of the reaction of a fitst order is twice the time required for the completion of a half of the reaction.

Answer»

SOLUTION :`t_((3)/(4))=(2.303)/(K)"log"([R]_(0))/((1)/(4)[R]_(6))`
`t_((3)/(4))=(2.303)/(K)log 4`
`= (2.303xx0.6021)/(K)=(1.386)/(K)`
`= 2xx(0.693)/(K)`
`= 2 t_((1)/(2))`


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