1.

Reactions involving stereoisomers To study the involvement of stereoisomers in chemical reactions we shall take up following points: (i)The conversion of an achiral molecule into a chiral molecule, with the generations of a chiral centre. Secondary butyl chloride exist as two enantiomers but mixture is optically inactive due to formation of a racemic mixture.Both enantiomers are obtained in equal amounts.Racemic mixture is an eqnimolar mixture of two enantiomers. (ii)Conversion of chiral molecule into chiral and achiral molecules. Which of the following reactant will give chiral products on monochlorination ?

Answer»

`CH_3-CH_2-CH_3`
`CH_3-undersetunderset(CH_3)(|)CH-CH_3`

SOLUTION :`CH_3-undersetunderset(CH_3)(|)CH-undersetunderset(CH_3)(|)CH-CH_3 OVERSET(Cl_2//hv)toCH_3-undersetunderset(CH_3)(|)CH-undersetunderset(CH_3)(|)CH-CH_2Cl` (CHIRAL PRODUCT)


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