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Redox reactions play a pivoted role in chemistry and biology. The values of standard redox potential and biology. The values of standard redox potential (E^0) of two half cell reactions decide which way the raction is expected to proceed. A simple example is a Daniel cell in which zinc goes into solution and copper gets deposited. Given below are a set of half-cell reactions (acidic medium) along with their E^0 (V with respect to normal hydrogen eletrode ) values. Using this dat obtain the correct explanations to Questions I_2+2e^_ rarr2I^-E^0=0.54 Cl_2+2e^_ rarr2Cl^-E^0=1.36 Mn^(3+)+e^_ rarrMn^(2+)E^0=1.50Fe^(3+)+e^_ rarrFe^(2+)E^0=0.77O_2+4H^++4e^(-) rarr 2H_2OE^0=1.23While Fe^(3+) is stable, Mn^(3+) is not stable in acid soltuion because

Answer»

`O_2` OXIDISES `MN^(2+)` to `Mn^(3+)`
`O_2` oxidises both `Mn^(2+)` to `Mn^(3+)` and `FE^(2+)` to `Fe^(3+)`
`Fe^(3+)` oxidises `H_2O " to " O_2`
`Mn^(3+)` oxidises `H_2O " to " O_2`

Answer :D


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