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Reduction of an alkyne to the double bond stage can yield a cis alkene or trans alkene (except in cases where triple bond is at the end of the chain ) Reduction of alknes with sodium or lithium in liquid NH_(3) yields predominantly trans alkene. Hydrogenation of alkynes with Lindlar's catalyst or a nickel boride called P_(2) catalyst yeilds is alkene (as high as 98%) If Pd/C/H_(2) is used in the absence of a catalyst poison, two equivlanet of H_(2) are added forming alkanes.Shown below is the first step in hte synthesis of hte important perfume constituent, cis-Jasmone which reagents you choose to carry out this last step? |
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Answer» `Li//NH_(3)` |
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