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Reduction of an alkyne to the double bond stage can yield a cis alkene or trans alkene (except in cases where triple bond is at the end of the chain ) Reduction of alknes with sodium or lithium in liquid NH_(3) yields predominantly trans alkene. Hydrogenation of alkynes with Lindlar's catalyst or a nickel boride called P_(2) catalyst yeilds is alkene (as high as 98%) If Pd/C/H_(2) is used in the absence of a catalyst poison, two equivlanet of H_(2) are added forming alkanes.Lindlar's catalyst can be prepared in precipitating palladium calcium carbonate and treating it with lead acetate or quinoline. This treatement is |
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Answer» partically deactivities the catalyst WHICHCAUSES REDUCTION of ALKYNE to alkene |
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