1.

Select the correct statement(s) with respect to the p pi-dpi dative bond.

Answer»

In `(Ph_3Si)_2O`, the Si-O-Si group is nearly linear
Silanols such as `(CH_3)_3` SiOH are stronger protonic acids then their carbon analogs
Trisilysl phosphine `(H_3Si)_3` P is planar
`CIO_4^-` does not polymerise at all

Solution :(A)Steric repulsions of bulkier groups and `ppi-DPI` dative bonding FAVOUR for a linear Si-O-Si group.
(B)Due to stabilization of the conjugate base anion by O `(ppi)to Si(dpi)`bonding MOTION.
( C)In is PYRAMIDAL because `ppi-dpi` bonding is not effective due to the bigger size of phosphorus atom
(D)Most effective due to small size of chlorine.


Discussion

No Comment Found

Related InterviewSolutions