1.

Show that SHE can act both as a anode as well as cathode.

Answer»

Solution :(i) When it is placed on the right-hand side of the zinc electrode, the hydrogen electrode reaction is,
`""2H^(+)+2E^(-) rarr H_(2)`
The electrons flow to the SHE and it acts as the cathode.
(ii) When the SHE is placed on the LEFT hand side, the electrode reaction is
`""H_(2) rarr 2H^(+)+2e^(-)`
The electrons flow to the copper electrode and the hydrogen electrode acts as the anode.


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