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SN I reaction undergoes through a carbocation intermediate as follows : R−X(aq.)Slow⇌R∗(aq.)+X−(aq.)H2O−−→fastROH(aq.)+H+(aq.) [R = t-Bu, iso-Pr, Et, Me] (X = Cl, Br, I) The correct statements are (I) The decreasing order of rate of SN 1 reaction is t-BuX > iso-PrX > EtX > MeX (II) The decreasing order of ionization energy is MeX > EtX > iso-PrX> t-BuX (III) The decreasing order of energy of activation is t-BuX > iso-PrX > EtX > MeX |
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Answer» SN I reaction undergoes through a carbocation intermediate as follows : R−X(aq.)Slow⇌R∗(aq.)+X−(aq.)H2O−−→fastROH(aq.)+H+(aq.) [R = t-Bu, iso-Pr, Et, Me] (X = Cl, Br, I) The correct statements are (I) The decreasing order of rate of SN 1 reaction is t-BuX > iso-PrX > EtX > MeX (II) The decreasing order of ionization energy is MeX > EtX > iso-PrX> t-BuX (III) The decreasing order of energy of activation is t-BuX > iso-PrX > EtX > MeX |
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