1.

SN I reaction undergoes through a carbocation intermediate as follows : R−X(aq.)Slow⇌R∗(aq.)+X−(aq.)H2O−−→fastROH(aq.)+H+(aq.) [R = t-Bu, iso-Pr, Et, Me] (X = Cl, Br, I) The correct statements are (I) The decreasing order of rate of SN 1 reaction is t-BuX > iso-PrX > EtX > MeX (II) The decreasing order of ionization energy is MeX > EtX > iso-PrX> t-BuX (III) The decreasing order of energy of activation is t-BuX > iso-PrX > EtX > MeX

Answer» SN I reaction undergoes through a carbocation intermediate as follows :
RX(aq.)SlowR(aq.)+X(aq.)H2OfastROH(aq.)+H+(aq.)
[R = t-Bu, iso-Pr, Et, Me] (X = Cl, Br, I)
The correct statements are
(I) The decreasing order of rate of SN 1 reaction is t-BuX > iso-PrX > EtX > MeX
(II) The decreasing order of ionization energy is MeX > EtX > iso-PrX> t-BuX
(III) The decreasing order of energy of activation is t-BuX > iso-PrX > EtX > MeX


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