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| 1. |
Some grignard reagents react with ethyl orthoformate followed by acidic hydrolysis to give aldehydes. Propose mechanisms for the two steps in this synthesis. H-underset(O-CH_(2)CH_(3))underset(|)overset(O-CH_(2)CH_(3))overset(|)(C)-O-CH_(2)CH_(3)+R-Mg-X rarr R-underset(H)underset(|)overset(O-CH_(2)CH_(3))overset(|)(C)-O-CH_(2)CH_(3) overset(H_(3)O^(+))(rarr)R-overset(O)overset(||)(C)-H ethyl orthofomate""acetal"" aldehyde |
| Answer» SOLUTION : R —Mg—X | |