1.

Standard electrode potential data are useful for understanding the suitability of an oxidant in a redox titration. Some half cell reactions and their standard potentials are given below: MnO_((aq))^- +8_((aq))^+ +5e to Mn_((aq))^(2+)+4H_2O_((l)), E^0=1.51V Cr_2O_(7(aq))^(2-)+14H_((aq))^+ +6e to MnO_(4(aq))^-+8H_((aq))^+ +6e to 2Cr_((aq))^(3+)+7H_2O_((l)),E^0=1.38V Fe_((aq))^(3+)+e^- toFe_((aq))^(2+),E^0=0.71V Cl_2(g)+2e^- to 2C_((aq))^-, E^0=1.40V Identify the only incorrect statement regarding the quantitive estimation of aqueous Fe(NO+3)_2

Answer»

`MnO_4^-` can be USED in aqueous HCL
`Cr_2O_7^(2-)` can be used in aqueous HCl
`MnO_4^-` can be used in aqueous `H_2SO_4`
`Cr_2O_7^(2-)` can be used in aqueous `H_2SO_4`

Solution :(D) it is the case of attacked electrode that is
ANODE: Cu `rarr Cu^(2+)`+2e,
CATHODE : `Cu^(2+)` +2e `rarr` Cu
Thus no change in CONC. Of `Cu^(2+)` ions.


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