1.

Standard electrode potential of Ag^(+)//Ag and Cu^(+)//Cu is +0.80V and +0.34V respectively. These electrodes are joint together by salt bridge if

Answer»

copper electrode WORK like anode then `E_(cell)^(o)` is +0.45V
Silver electrode work like anode then `E_(cell)^(o)` is -0.34V
Copper electrode work like anode then `E_(cell)^(o)` is +0.46V
Silver electrode work like cathode then `E_(cell)^(o)` is-0.34V

Solution :Cell reaction is
`Cu_((s))+2AG^(+)toCu^(2+)+2Ag`
Two half cell reaction
`CutoCu^(2+)+2e^(-)"Oxidation (anode)"`
`AG^(+)+e^(-)TOAG"Reduction (cathode)"`
`E_(cell)=E_(o x)-E_(red)=0.80-0.34=+0.46V`


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