1.

Standard reduction potentials for the half reactions are given below : F_(2)(g)+2e^(-) to 2F^(-)(aq) , E^(@)=+2.85" V " Cl_(2)(g)+2e^(-) to 2Cl^(-)(aq) , E^(@)=+1.36" V " Br_(2)(g)+2e^(-) to 2Br^(-)(aq) , E^(@)=+1.06" V " I_(2)(g)+2e^(-) to 2I^(-)(aq) , E^(@)=+0.53" V " The strongest oxidising and reducing agents respectivity are :

Answer»

`F_(2)` and `I^(-)`
`Br_(2)` and `Cl^(-)`
`Cl_(2)` and `Br^(-)`
`Cl_(2)` and `I_(2)`.

SOLUTION :(a) More negative (or less positive) the VALUE of reduction potential, stranger will be the reducing agent. Thus `L^(-)` is the STRONGEST reducing agent. More positive is the values of reduction potential, stronger will be the oxidising agent. Thus, `F_(2)` is the strongest oxidising agent.


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