1.

Statement 1: The standard emf (E_(cell)^(@)) of following concentration cell is zero. Zn(s)|ZnSO_(4)(C_(1))||ZnSO_(4)(C_(2))|Zn(s) Statement 2: The electrolyte concentration cell will be is greater in cathodic half-cell.

Answer»

Statement 1 is true, statement 2 is true, statement 2 is a correct explanation for statement 1
Statement 1 is true, statement 2 is true, statement 2 is not a correct explanation for statement 1
Statement 1 is true, statement 2 is false
statement 1 is false,statement 2 is true

Solution :`E_(cell)^(o)=E_("Cathode")^(o)-E_("anode")^(o)`
=0 for all concentration cells
`E=(0.059)/(N)log_(10)((C_(2))/(C_(1)))` (for the given cell) LTBR the cell will be spontaneous (E=+ve) when `C_(2)` is greater than `C_(1)`, i.e., concentrtion in cathodic half-cell is greater than that of ANODIC half-cell.


Discussion

No Comment Found