1.

Statues and paintings coated with white lead turn black on long exposure to atmoshphere. The original colour can be restored by treating them with H_(2)O_(2) The reason behind this is

Answer»

blackened statues get coated with PbS which on reaction with `H_(2)O_(2)`is oxidised to white `PbSO_(4)`
`H_(2)O_(2)`DISSOLVES the coating of white lead and exposes the inner surface.
white lead reacts with `H_(2)O_(2)`to form white `PbSO_(4)`
blackened statues get coated with lead sulphate which reacts with `H_2O_(2)` to give PbS.

Solution :The statues and paintings coated with white lead get blackened DUE to ACTION of `H_(2)O` present in traces in atmosphere. When these are treated with `H_(2)O_(2)`, PbS is oxidised to `PbSO_(4)` which is colourless or white.
`underset("Black")(PbS)+4H_(2)O_(2)RARR underset("White")(PbSO_(4))+4H_(2)O`


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