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Suggest a reason why HF is a weak acid, whereas binary acids of the all other halogens are strong acids. |
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Answer» The hydrogen halides are extremely soluble in water due to the ionisation. X + H2O → H3O+ + X- (X = F, Cl, Br or I) Solutions of hydrogen halides are therefore acidic and known as hydrohalic acids. Hydrochloric, hydrobromic and hydroiodic acids are almost completely ionised and are therefore strong acids but HF is a weak acid. For HF,
At high concentration, the equilibrium involves the removal of fluoride ions is important. Since it affects the dissociation of hydrogen fluoride, therefore it is a weak acid. |
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