1.

The additio of HBr to but-1-ene gives a mixture of products (I),(II) and (III). . (III). CH_(3)-CH_(2)-CH_(2)-CH_(2)-Br. Mixture consists of

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(I) and (II) as MAJOR and (III) as MINOR PRODUCTS
(II) as major, (I) and (III) as minor products.
(II) as minor, (I) and (III) as major products.
(I) and (II) as minor and (III) as major products.

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