1.

The best method to prepare neopentyl chloride is (CH_(3))_(3)C-CH_(2)-OHoverset(PCl_(5)//Delta)to ( B) (CH_(3))_(3)C-CH_(2)-OHoverset(HCl//Delta)to © (CH_(3))_(3)C-CH_(2)-OHoverset(SOCl_(2)//"Pyridine")to (D) (CH_(3))_(3)C CH_(3)overset(Cl_(2)//hv)underset(Delta)to

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Solution :
On the other hand, free radicals do not undergo REARRANGEMENT. HENCE, the BEST method of preparation is throough free radical CHLORINATION.


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